CHEMICAL HYGIENE PROGRAM
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Appendix 5
Incompatible Chemicals
The following are common examples of incompatible combinations:
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Chemical
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Keep out of contact with:
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Acetic Acid
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perchloric acid, nitric acid, chromic
acid, hydroxyl compounds, peroxides, permanganates
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Acetylene
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chlorine, bromine, copper, fluorine,
silver, mercury
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Alkali Metals (e.g. Sodium)
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water, chlorinated hydrocarbons, carbon
dioxide, halogens
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Ammonia, Anhydrous
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mercury, chlorine, calcium hypochlorite,
iodine, bromine, hydrofluoric acid
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Ammonium Nitrate
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acids, metal powders, flammable liquids,
chlorates, nitrites, sulfur, finely divided combustible materials
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Aniline
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nitric acid, hydrogen peroxide
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Bromine
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same as chlorine
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Carbon, Activated
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calcium hypochlorite, all oxidizing agents
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Chlorates
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ammonium salts, acids, metal powders,
sulfur, finely divided combustible materials
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Chromic Acid
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acetic acid, naphthalene, camphor, glycerin,
turpentine, alcohol, flammable liquids
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Chlorine
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ammonia, acetylene, butadiene, butane,
methane, propane (or other petroleum gases), hydrogen, sodium carbide,
turpentine, benzene, finely divided metals
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Copper
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acetylene, hydrogen peroxide
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Flammable Liquids
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ammonium nitrate, inorganic acids, hydrogen
peroxide, sodium peroxide, halogens
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Hydrocarbons
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fluorine, chlorine, bromine, chromic
acid, sodium peroxide
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Hydrofluoric Acid
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anhydrous ammonia, ammonium hydroxide
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Hydrogen Peroxide
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copper, chromium, iron, most metals or
their salts, alcohol, acetone, aniline, nitromethane, flammable liquids,
oxidizing gases
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Hydrogen Sulfide
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fuming nitric acid, oxidizing gases
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Iodine
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acetylene, ammonia (aqueous or anhydrous),
hydrogen
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Mercury
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acetylene, fulminic acid, ammonia
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Nitric Acid
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acetic acid, aniline, chromic acid, hydrocyanic
acid, hydrogen sulfide, flammable liquids, flammable gases
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Oxalic Acid
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silver, mercury
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Perchloric Acid
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acetic anhydride, bismuth and its alloys,
organic materials
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Potassium
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carbon tetrachloride, carbon dioxide,
water
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Potassium Chlorate
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sulfuric and other acids
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Potassium Permanganate
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glycerin, ethylene glycol, benzaldehyde,
sulfuric acid
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Silver
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acetylene, oxalic acid, tartaric acid,
ammonia compounds
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Sodium Peroxide
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alcohol, glacial acetic acid, acetic
anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene, glycol,
ethyl acetate, methyl acetate, furfural
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Sulfuric Acid
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potassium chlorate, potassium perchlorate,
potassium permanganate (or compounds with similar light metals, such as
sodium, lithium, etc.)
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Consult the MSDS for the chemicals in your location for additional information
on incompatible chemicals.
QUESTIONS? Contact EH&S at (585) 275-3241 or e-mail EH&S Questions.
This page last updated 2/17/2006. Disclaimer
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